Safety Data Sheet

Section 1 – Identification

1.1 Product Identifier

Product Form: Mixture

Product Name: Flame Retardant Solutions

Chemical Family: A halogen-free aqueous solution of acids and salts.

1.2 Other Means of Identification

Halogen-free water-based flame retardant that does not contain Fluorine, Chlorine, Bromine, Iodine or Astatine, which may release dangerous substances.

1.3 Recommended Use

Water-based flame retardant for the treatment of fabrics, natural fibres and wood.

1.4 Supplier Details

Flame Retardant Solutions (Pty) Ltd
18 Hawthorne Close
Dennendal
Cape Town
7945
South Africa

1.5 Emergency Telephone Number

+27 082 452 1499

Section 2 – Hazard Identification

Classification

  • Reproductive Toxicity – Category 1B
  • Hazardous to the Aquatic Environment (Acute) – Category 3

Signal Word

Danger

Hazard Statements

  • H360 – May damage fertility or the unborn child.
  • H402 – Harmful to aquatic life.

Precautionary Statements

  • P201 – Obtain special instructions before use.
  • P202 – Do not handle until all safety precautions have been read and understood.
  • P273 – Avoid release to the environment.
  • P280 – Wear protective gloves, protective clothing and eye protection.
  • P308 + P313 – IF exposed or concerned: Get medical advice/attention.
  • P405 – Store locked up.
  • P501 – Dispose of contents/container in accordance with local regulations.

Other Hazards

No additional hazards identified under normal conditions of use.

Section 3 – Composition / Information on Ingredients

This product is a mixture.

Component Classification
Inorganic sulphate salt Aquatic Acute 3 (H402)
Boric Acid Reproductive Toxicity 1B (H360)
Aquatic Acute 3 (H402)

Section 4 – First Aid Measures

General Advice

If exposed or concerned, obtain medical advice or attention.

Eye Contact

Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical advice if irritation persists.

Skin Contact

Wash skin thoroughly with soap and water. Remove contaminated clothing. Seek medical advice if irritation develops.

Inhalation

Move the affected person to fresh air. Keep at rest. Seek medical attention if symptoms continue.

Ingestion

Rinse mouth thoroughly. Do not induce vomiting unless directed by medical personnel. Seek medical advice immediately.

Most Important Symptoms

  • Respiratory irritation
  • Skin irritation
  • Eye irritation
  • Nausea
  • Vomiting
  • Diarrhoea
  • May damage fertility or the unborn child

Notes to Physician

Treat symptomatically.

Section 5 – Fire-fighting Measures

5.1 Suitable (and Unsuitable) Extinguishing Media

Suitable Extinguishing Media

Will not normally support combustion.

Unsuitable Extinguishing Media

None known.

5.2 Specific Hazards Arising from the Chemical

Products of combustion may include, but are not limited to, oxides of carbon.

5.3 Special Protective Actions for Fire-fighters

Keep upwind of the fire. Wear full fire-fighting protective clothing (full bunker gear) together with self-contained breathing apparatus (SCBA).

Section 6 – Accidental Release Measures

6.1 Personal Precautions, Protective Equipment and Emergency Procedures

General Measures

Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel.

For Non-Emergency Personnel

No additional information available.

For Emergency Responders

No additional information available.

6.2 Environmental Precautions

Prevent entry to sewers and public waters. Notify authorities if the product enters sewers or public waters.

6.3 Methods and Materials for Containment and Cleaning Up

Containment

Absorb and/or contain spill with inert material (sand, vermiculite or other suitable material), then place in an appropriate container. Do not flush into surface water or sewer systems. Wear recommended personal protective equipment.

Clean-Up Methods

Sweep or shovel spilled material into an appropriate container for disposal. Provide adequate ventilation during clean-up.

Section 7 – Handling and Storage

7.1 Precautions for Safe Handling

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.

  • Avoid contact with skin and eyes.
  • Avoid breathing dust, fumes, gas, mist, vapours or spray.
  • Do not swallow.
  • Handle and open containers with care.
  • Do not eat, drink or smoke while using this product.

Hygiene Measures

  • Wash contaminated clothing before reuse.
  • Always wash hands thoroughly after handling the product.

7.2 Conditions for Safe Storage

  • Keep out of reach of children.
  • Keep container tightly closed.
  • Store in a dry, cool and well-ventilated area.
  • Store locked up.
  • Refer to Section 10 for incompatible materials.

Section 8 – Exposure Controls / Personal Protection

8.1 Control Parameters

No additional information available for Flame Retardant Solutions.

Boric Acid (CAS No. 10043-35-3)

Exposure Limit Value
ACGIH OEL TWA 2 mg/m³ (Inhalable particulate matter)
ACGIH OEL STEL 6 mg/m³ (Inhalable particulate matter)
Carcinogen Classification Not Classifiable as a Human Carcinogen

8.2 Appropriate Engineering Controls

  • Ensure good ventilation of the work area.
  • Avoid release into the environment.
  • Handle in accordance with good industrial hygiene and safety practice.
  • Do not eat, drink or smoke when using this product.

8.3 Personal Protective Equipment

Hand Protection

Wear suitable protective gloves. Consult the glove manufacturer’s recommendations regarding material suitability and thickness.

Eye Protection

Safety glasses or goggles are recommended.

Skin and Body Protection

Wear suitable protective clothing.

Respiratory Protection

If ventilation is insufficient, wear suitable respiratory protection. Respirator selection should be based on exposure levels and performed by a qualified person.

8.4 Exposure Limits for Other Components

No additional information available.

Section 9 – Physical and Chemical Properties

9.1 Basic Physical and Chemical Properties

Property Value
Physical StateLiquid
AppearanceClear Liquid
ColourClear
OdourOdourless
Odour ThresholdNo data available
pHNo data available
Boiling PointNo data available
Freezing PointNo data available
Flash PointNo data available
Auto-Ignition TemperatureNo data available
Decomposition TemperatureNo data available
FlammabilityNot flammable
DensityNo data available
Water Solubility100%
Vapour PressureNo data available
Relative DensityNo data available
ViscosityNo data available
Explosive PropertiesNo data available
Oxidising PropertiesNo data available
Lower Explosion LimitNo data available
Upper Explosion LimitNo data available

9.2 Data Relevant to Physical Hazard Classes

No additional information available.

Section 10 – Stability and Reactivity

10.1 Reactivity

No dangerous reactions known under normal conditions of use.

10.2 Chemical Stability

Stable under normal conditions.

10.3 Possibility of Hazardous Reactions

No dangerous reactions known under normal conditions of use.

10.4 Conditions to Avoid

Incompatible materials.

10.5 Incompatible Materials

Metals.

10.6 Hazardous Decomposition Products

May include, but are not limited to, oxides of carbon.

Section 11 – Toxicological Information

11.1 Information on Toxicological Effects

Property Classification / Information
Acute Toxicity (Oral) Not classified.
Acute Toxicity (Dermal) Not classified.
Acute Toxicity (Inhalation) Not classified.
Skin Corrosion / Irritation Not classified.
Serious Eye Damage / Irritation Not classified.
Respiratory or Skin Sensitisation Not classified.
Germ Cell Mutagenicity Not classified.
Carcinogenicity Not classified.
Reproductive Toxicity May damage fertility or the unborn child.
STOT – Single Exposure Not classified.
STOT – Repeated Exposure Not classified.
Aspiration Hazard Not classified.

Unknown Acute Toxicity

21.43% of the mixture consists of ingredient(s) of unknown acute toxicity (inhalation – vapours).

Acute Toxicity Data

Substance Result
Inorganic Sulphate Salt LD50 Oral (Rat): 2840 mg/kg
Inorganic Sulphate Salt LD50 Dermal (Rat): >2000 mg/kg
Boric Acid LD50 Oral (Rat): 2660 mg/kg
Boric Acid LD50 Dermal (Rabbit): >2000 mg/kg
Boric Acid LC50 Inhalation (Rat): >2.12 mg/l/4h

Chronic Toxicity

Inorganic sulphate salt (Trade Secret)

  • NOAEL (Male Rat – 2 years): 256 mg/kg bodyweight.
  • NOAEL (Female Rat – 2 years): 284 mg/kg bodyweight.

Other Information

Likely routes of exposure include ingestion, inhalation, skin contact and eye contact.

Section 12 – Ecological Information

12.1 Toxicity

General Ecology: Harmful to aquatic life.

Short-term (Acute): Harmful to aquatic life.

Long-term (Chronic): Not classified.

12.2 Persistence and Degradability

Persistence and degradability have not been established.

12.3 Bioaccumulative Potential

Bioaccumulative potential has not been established.

Inorganic Sulphate Salt

  • Log Kow: -5.1 (25°C)

Boric Acid

  • Bioconcentration Factor (BCF): 0
  • Log Kow: -1.09 (22°C, pH 7.5)

12.4 Mobility in Soil

No additional information available.

12.5 Other Adverse Effects

  • Not classified as ozone depleting.
  • No additional adverse environmental effects known.
  • No other effects known.

Section 13 – Disposal Considerations

13.1 Disposal Methods

Dispose of contents and container at a hazardous or special waste collection facility in accordance with local, regional, national and international regulations.

Waste generation should be avoided or minimised wherever possible.

Section 14 – Transport Information

This product is not regulated for transport in accordance with SANS, IMDG and IATA transport regulations.

14.1 UN Number

Not regulated for transport.

14.2 UN Proper Shipping Name

Regulation Proper Shipping Name
SANS Not applicable
IMDG Not applicable
IATA Not applicable

14.3 Transport Hazard Class(es)

Regulation Hazard Class
SANS Not applicable
IMDG Not applicable
IATA Not applicable

14.4 Packing Group

Regulation Packing Group
SANS Not applicable
IMDG Not applicable
IATA Not applicable

14.5 Environmental Hazards

Hazard Status
Dangerous for the Environment No
Marine Pollutant No

No supplementary transport information available.

14.6 Special Precautions for User

Do not handle until all safety precautions have been read and understood.

Transport Mode Information
SANS No data available
IMDG No data available
IATA No data available

14.7 Transport in Bulk According to IMO Instruments

Not applicable.

Section 15 – Regulatory Information

15.1 Safety, Health and Environmental Regulations

This Safety Data Sheet has been prepared in accordance with the following South African legislation and standards:

  • SANS 10234:2019
  • SANS 11014:2010
  • SANS 10228:2012
  • SANS 10229:2010
  • SANS 10232 (Parts 1, 2 & 4)
  • SANS 10231:2018
  • Occupational Health and Safety Act 85 of 1993
  • National Road Traffic Act 93 of 1996

Section 16 – Other Information

Company Statement

Our company slogan encapsulates our commitment to providing a reliable defence against the destructive power of fire. Just as a shield protects against external threats, our flame retardant solutions act as a protective barrier, preventing the rapid spread of flames and enhancing fire safety across diverse applications.

We stand as your shield, ensuring safety and security in the face of fire’s fury.

Document Information

Issue Date 04 March 2024
Revision Date 04 March 2024
Expiry Date 04 March 2029
Prepared By Nexreg Compliance Inc.
Website www.nexreg.com

Abbreviations and Acronyms

Abbreviation Description
ASTMAmerican Society for Testing and Materials
BCFBioconcentration Factor
BOD/CODBiochemical Oxygen Demand / Chemical Oxygen Demand
CASChemical Abstract Service
CBIConfidential Business Information
ECOSOCEconomic and Social Council of the United Nations
EINECSEuropean Inventory of Existing Commercial Chemical Substances
EUEuropean Union
GESAMPJoint Group of Experts on the Scientific Aspects of Marine Environmental Protection
GHSGlobally Harmonized System
IAEAInternational Atomic Energy Agency
IARCInternational Agency for Research on Cancer
ILOInternational Labour Organization
IMOInternational Maritime Organization
ISOInternational Standards Organization
IUPACInternational Union of Pure and Applied Chemistry
NOECNo Observed Effect Concentration
OECDOrganisation for Economic Co-operation and Development
PCBPolychlorinated Biphenyl
ppmParts Per Million
PVCPolyvinyl Chloride
rpmRevolutions Per Minute
QSARQuantitative Structure-Activity Relationship
SARStructure Activity Relationship
SDSSafety Data Sheet
SPRStructure Property Relationship
UNUnited Nations
UNCEDUnited Nations Conference on Environment and Development
UNCETDG/GHSUnited Nations Committee of Experts on the Transport of Dangerous Goods and on the Globally Harmonized System
UNSCETDGUnited Nations Sub-Committee of Experts on the Transport of Dangerous Goods
UNSCEGHSUnited Nations Sub-Committee of Experts on the Globally Harmonized System
WHOWorld Health Organization
WMOWorld Meteorological Organization

Hazard Statements

Code Description
H360 May damage fertility or the unborn child.
H402 Harmful to aquatic life.

Disclaimer

We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies only to the specific material supplied. It may not be valid if the material is used in combination with other materials. It is the user’s responsibility to determine the suitability and completeness of this information for their particular application.

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